Have the Z-Ring. You get the Z-Ring relatively early on, by completing the ceremonial battle at Iki Town against Hau at the beginning of the game.
Have your Pokémon hold an appropriate Z-Crystal. This can be done by going in to your bag, selecting the “Items” and finding the Z-Crystal you want to equip your Pokémon with. Some Z-Crystals are for Pokémon that know a move of a specific type (for example, the Normalium Z is for Pokémon that know a Normal-type move), while others can be used only on a single Pokémon (such as the Snorlium Z, which can only be used with Snorlax). If a Pokémon does not meet the specifications of a Z-Crystal (for example, if they don’t know a Normal-Type move or they aren’t a Snorlax), then you won’t even be able to equip them with that Z-Crystal.
Go into a Pokémon battle. It can be any type of battle - a battle with a wild Pokémon, a trainer battle, a battle with your rival, or even a battle with a Totem Pokémon.
Select the "Z-Power" option on the left side of the bottom screen. Then, confirm the Z-Move that you’d like to use. Your Pokémon will then complete the Z-Move, which varies depending on the Z-Crystal you give it.
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